Analysis Of The Poem The Accident - 922 Words

The Accident By, Madalynn Gienau â€Å"Come here everybody watch this!† I exclaimed. Everybody crowded around, and I took a running start. I had practiced and practiced and I was now ready to show everybody what I could do. I leapt off the yellow monkey bar platform trying to reach the cold metal of the fourth ring. All I can remember is ending up on the hard pointy wood chips. Everyone was in shock and didn’t know what to do. â€Å"Somebody help, what are you guys doing, look at me,† I said balling. Nobody did anything, they just kept staring. Not even a teacher came. I felt helpless lying on the wood chips holding my â€Å"S† shaped wrist. I didn’t know what to do. Eventually, about one minute later, a teacher heard me crying. Mrs.†¦show more content†¦Kim as she comforted me. I just kept balling. The school kept trying to call my mom, but she was not answering. The school then called my grandma to come and get me. My grandma showed up and rushed into the nurse s office. My grandma removed the cold ice pack from my wrist to see what was wrong. Her and I immediately rushed to her van and started to drive away. While we were driving my grandma kept trying to call my mom and finally got a hold of her. Right as we pulled out of Prescott parking lot my mom pulled in. Me and my grandma turned around and I got into my mom s van and we were now headed to the hospital for sure. While we were driving every bump in the road moved my wrist and it hurt. When we arrived at the emergency room, they immediately took me back and got me settled into a room. The nurse came in and wanted to start an IV to give me pain medication. The doctor examined me and decided I needed X-rays. They wheeled me over to the X-ray room where it was dark and chilly. They then took X-rays of my right wrist. It hurt to have the X-rays done because of the way they positioned my arm. They took me back to my room and the doctor came in and told my mom that my wrist was broken in two places. He also told her they would have to put me to sleep to set my wrist. We waited for what seemed like hours for the doctor to take me to the operating room. It was so hard to get comfortable because it hurt to move my wrist. While

Are the Classical Management Functions useful in...

Are the Classical Management Functions Useful in Describing Managerial Work? Author(s): Stephen J. Carroll and Dennis J. Gillen Source: The Academy of Management Review, Vol. 12, No. 1 (Jan., 1987), pp. 38-51 Published by: Academy of Management Stable URL: http://www.jstor.org/stable/257992 . Accessed: 08/09/2014 02:29 Your use of the JSTOR archive indicates your acceptance of the Terms Conditions of Use, available at . http://www.jstor.org/page/info/about/policies/terms.jsp . JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new†¦show more content†¦McCall and Segrist (1980) found that the activities found in four of Mintzberg s ten roles (figurehead, disseminator, disturbance handler, and negotiator) overlapped too much with the activities found in other roles to be considered separate. Also an examination of the McCall and Segrist (1980) factor loadings for the items they used to measure Mintzberg s roles indicates that many of the items for the remaining six Mintzberg role scales also loaded heavily on several factors rather than one. Lau, Newman, and Broedling (1980) used Mintzberg s framework to develop 50 questionnaire items which were administered to 210 government managers and then factor analyzed. Instead of Mintzberg s ten roles, they found four factors (leadership and supervision, information gathering and dissemination, technical problem solving, and executive decision making-planning-resource allocation). Although this study indicated that managers spend some time in leadership as well as in information gathering and dissemination activities as Mintzberg indicated, it was not supportive of Mintzberg s findings. Kurke and Aldrich (1983) observed four top executives (two public/two private) for one week. Using Mintzberg s coding categories, they found these managers carried out a large number of different activities per day, that the jobs wereShow MoreRelatedContemporary Management1199 Words   |  5 PagesIRHR1001- Essay The Primary Article is: Carroll, S. and Gillen, D. (1987) Are the Classical Management Functions Useful in Describing Managerial Work? Academy of Management Review 12(1), pp. 38-51. The essay will endeavor to provide an insight into how Fayol’s basic principles of Classical Management Functions are indeed useful in describing managerial work. In the last (20th) century, the role of managers in business becomes more diverse as the number of tasks in which businesses were involvedRead MoreAre the Classical Functions Put Forward by Henri Fayol in 1949 Still Valid and True Today?1263 Words   |  6 Pagesthe effectiveness of classical approaches to newer conceptualizations within management functions. 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Management functions, roles, and skills, have been labelled as the three distinctive categories to aid the job description of managers (Robbins, Bergman, Stagg Coulter, 2006). The purpose of this essay is to identify the work that is required from a manager of today, and evaluate the comparisons with the characterisations created by past management researchers, and theirRead MoreManagement Theory Essay2106 Words   |  9 Pagesthese ideas. The following essay will compare and contrast the ideas of Fayol and Mintzberg relating to management which have been developed to assist a manger to complete their job of working with and through others so that organisations can achieve goals and objectives efficiently and effectively. This shall be done by using academic sources and reference materials relevant to management. The essay will briefly outline the basis features of Fayol’s theory along with that of Mintzberg. From thisRead MoreFayol s Theory Of Management Essay1570 Words   |  7 PagesHenri Fayol s managerial activities are recognized as being essential and are specially emphasized as being universal for achieving an organization s goals (Pugh and Hickson, 1964). The undeniable contribution to management has provided a system of concepts which has become a leading guide for managers in most organizations. Though there were few authors who weren t affected by Fayol s work, there were some who criticized his wor k as being idealist and ignoring the reality of management. MintzbergRead Moremanagement functions2151 Words   |  9 Pagesï » ¿MANAGEMENT FUNCTIONS The functions of management uniquely describe managers jobs. The most commonly cited functions of management are planning, organizing, leading, and controlling, although some identify additional functions. The functions of management define the process of management as distinct from accounting, finance, marketing, and other business functions. These functions provide a useful way of classifying information about management, and most basic management texts since the 1950sRead MoreManagement: Fayol vs Mintzberg2042 Words   |  9 Pagesdiscuss the extent to which Fayols classical analysis of the management function has largely been made redundant by the more recent empirical studies of what managers actually do, such as that favoured by Mintzberg. Introduction Henri Fayol, at the age of 19, began working as engineer at a large mining company in France which eventually led to him becoming a director. Through the years that led on to this Fayol then developed his 14 principles of management which he considered to be the mostRead MoreTaylors Principles of Management Essay1472 Words   |  6 PagesIn this 21st century, management has been observed as both art and science (Reh, 2010). It is an art as it helps people to be more innovative, creative, and effective on doing their job, compare with the previous time when people would have been doing their job without applying the knowledge of management. Likewise, management can be considered as a science in how managers will be able to manage people and help them to involve further and to be more effective. The term of manager here refers to the

Mr Guan Free Essays

Report Report Due: pm Friday 23rd August, Week 4. Hand in report electronically vie e-learning. Time to complete: This assessment task should take the average student 10-15 hours to complete, Including research time. We will write a custom essay sample on Mr Guan or any similar topic only for you Order Now Late Penalty: As for all other assessment tasks for this course, late penalties are 20% of the maximum possible mark per day or part thereof. Time of submission Is logged via e-learning, note that the e-learning time may not be the same as your watch/phone/computer timely Weekends and public holidays are not included . Plagiarism: You must include a plagiarism compliance statement. Reports may be checked for plagiarism with an online system, please correctly use quotes from sources and reference them correctly as per the author/ date or numbered system. Refer to the library weapon for guidance on referencing and plagiarism. Any report found to have been plagiarisms will be processed as per the University plagiarism policy. Task Description: Written case study report (20% of course total assessment). Present a written technical (In report format as per lecture one guidelines) case study focusing on a major workplace safety incident that occurred (anywhere In the world). The emphasis and purpose of the report Is to; research, describe and discuss the Incident primarily In relation to the Safety Systems related to the event. Ђ Describe the Incident/event and possible causes of the event (including causes related to the management/operation of safety systems) Relate the incident/event to any failures in safety systems (including managerial) that were present Discuss what preventative measures could/should have been taken What changes would you suggest be made to limit the possibility of repeat event occurring? How would you review the effectiveness of your proposed changes? Word Limit: This Report should be approximately 2000-3000 words in length (not including the title page, summary, table of contents, references or appendices). Writing concise yet Informative reports Is an Important part of being a Professional Engineer. The ability to accurately convey Information In a concise, relevant and effective manner is a key skill that you should endeavourer to develop. Reports containing more than 3250 or fewer than 1750 words will result in mark penalties of 0% of the possible mark for every 250 words under/ over the limit. Grade Descriptors A+ A ABA+ B BIO 95 90 85 80 75 High Distinction 85% – 100% As for the criteria for ‘Distinction’, however the work also shows a high degree of professionalism. The report structure is excellent and provides a convincing discussion/argument of the topic. There is good evidence of in depth, critical discussion of the topic. Report has excellent grammar, spelling and Is of a concise nature. The work shows a good appreciation of the general alma/purpose of the topic. There Is good coverage of the topic with relevant and accurate support ND a well developed scholarly discussion/argument. Grammar and spelling are very good and report is reasonably concise. The work is relevant and addresses several reasonable amount of the content and a scholarly discussion/argument has been advanced. There is limited evidence of an overall integrative view of the topic. Grammar, spelling and conciseness are lacking. The information in the various aspects of the work is relevant and accurate but is not integrated and only covers some core aspects of the topic. There is an attempt at a scholarly discussion/ argument and the work indicates a limited understanding of the topic. How to cite Mr Guan, Papers

Biological Molecules free essay sample

What is the building block of a carbohydrate? Monosaccharides Amino acids are found in which type of macromolecule? Polypeptide Name 2 molecules that you constructed that contain carboxylic acid groups. 1. Carboxyl 2. Glycine Name 2 molecules that you constructed that contain hydroxyl groups. 1. Alanine 2. Glucose Explain the difference in structure between saturated and unsaturated fatty acids. Why is this difference important in the body? Saturated fats have one fatty acid chain with a single covalent bond between the carbon atoms. Unsaturated fatty acids have 2 or more double bonds between the carbon atoms. The longer fatty acids chains found in saturated fats are packed closely together, which causes to form a solid. Unsaturated fats are short and cannot be packed to together because of the double bond. 6. Match the following molecules to their correct description F. sucrose C. oleic acid E. cholesterol A. glucose D. glycine A. fructose D. alanine B. butyric acid a. monosaccharide b. We will write a custom essay sample on Biological Molecules or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page saturated fatty acid c. unsaturated fatty acid d. amino acid e. steroid f. disaccharide 7. Identify each of the following molecules, using the following choices: glucose, glycerol, amino acid, saturated fatty acid, unsaturated fatty acid, steroid a. Glucose is sugar and a monosasscharide https://encrypted-tbn3. google. com/images? q=tbn:ANd9GcSKbRmke51q2-2MyqxvlGmGwXhDDE-VEnnCUmVsZXtDX-c_rYX8 b. Glycerol is a modified simple sugar and a triglyceride c. Amino Acids on the building blocks of protein d. Saturated fatty acid are single covalent bonds between carbon atoms e. Unsaturated fatty acids are 2 or more double bonds between carbon atoms. f. Steroid are flat molecules made up of four interlocking hydrocarbon rings. For questions 8-9, use the following key: Black carbon? Red oxygen? Blue nitrogen? White hydrogen 8. Identify the following molecules and fill in the table below. A. O~H~O (white-blue-white) B. O~O (Blue-Blue) C. H H~ C~H (white-white-red-white-white) H D. O~C~O (blue-red-blue) IMG_3674 Chemical? Formula Letter in ? Above Photo H2O Water O2 Oxygen Gas CH4 Methane CO2 Carbon dioxide 9. Identify the following TYPE of molecules (for example, monosaccharide, amino acid, etc).

States by Edward Said Essay Example

States by Edward Said Paper Taylor Stephan Section 2 Exam â€Å"States† 1. Edward Said emphasizes the scattered, alienated nature of the Palestinian people. In my opinion, Said clearly displays that it is unfair to ask â€Å"What is it you Palestinians want? †. Palestine, once recognized as a country and a community, is now shattered into a plethora of pieces. These pieces, or people each with memories and experiences, were sprinkled all across the world. It would seem impossible to share national pride when one’s country does not technically exist. Palestinians do not have a unified home where they can share their sense of culture and their similar beliefs. Many Palestinians â€Å"speak of awdah (return)† (650). They want to restore their country, and glue together the broken pieces. Even if Palestine could be restored as a country, would it ever be the same? One cannot erase history. The Palestinians can never truly regain what they want, which is their identity and ethnocentricity. Questions can easily be misinterpreted. Misunderstandings due to poor communication have appeared throughout history. For example, in the 1940’s, America threatened Japan with an embargo, unless they cut relations with Japan. The Japanese mistakenly took this as a threat to their national security. The confusion caused the attack on Pearl Harbor, which is an extremely important event in American history. Japan and the United States were opposing forces, but trade held together the peace. This misunderstanding caused more hostility between the two groups. 2. Said explains that the photograph ignites negative, yet positive feelings about the condition of the Palestinian people. Said shows that this picture reflects symbols of vulnerability and disarray throughout the Palestinians. We will write a custom essay sample on States by Edward Said specifically for you for only $16.38 $13.9/page Order now We will write a custom essay sample on States by Edward Said specifically for you FOR ONLY $16.38 $13.9/page Hire Writer We will write a custom essay sample on States by Edward Said specifically for you FOR ONLY $16.38 $13.9/page Hire Writer This shabby house, near Senjel, is covered with weeds. It appears to be out of place under the coverage of the trees. Said is very passionate for his own people. He has a great deal of emotional discomfort seeing a photographic display of the dislocation of his own people. I do not know what it feels like to lose my identity and be viewed through a skeptic’s eyes. Although this picture does not appear to incite certain emotions and feelings in myself, it is plausible for Said connect his feelings. Said understands the meaning of displacement with regards to his people’s history. Extra Credit: I can still remember the tragedy of September 11th. I was in second grade. All of the students were immediately sent home or picked up by their parents. I did not understand the images on the news. It almost seemed like a surreal action film. My aunt was on a flight to New York City that day, but luckily she arrived safe. I respect the people and rescue crew involved during September 11th. I think they displayed a deep sense of care for fellow Americans. I hope that the directly affected families have some sense of peace all of these years later. States by Edward Said Essay Example States by Edward Said Paper Taylor Stephan Section 2 Exam â€Å"States† 1. Edward Said emphasizes the scattered, alienated nature of the Palestinian people. In my opinion, Said clearly displays that it is unfair to ask â€Å"What is it you Palestinians want? †. Palestine, once recognized as a country and a community, is now shattered into a plethora of pieces. These pieces, or people each with memories and experiences, were sprinkled all across the world. It would seem impossible to share national pride when one’s country does not technically exist. Palestinians do not have a unified home where they can share their sense of culture and their similar beliefs. Many Palestinians â€Å"speak of awdah (return)† (650). They want to restore their country, and glue together the broken pieces. Even if Palestine could be restored as a country, would it ever be the same? One cannot erase history. The Palestinians can never truly regain what they want, which is their identity and ethnocentricity. Questions can easily be misinterpreted. Misunderstandings due to poor communication have appeared throughout history. For example, in the 1940’s, America threatened Japan with an embargo, unless they cut relations with Japan. The Japanese mistakenly took this as a threat to their national security. The confusion caused the attack on Pearl Harbor, which is an extremely important event in American history. Japan and the United States were opposing forces, but trade held together the peace. This misunderstanding caused more hostility between the two groups. 2. Said explains that the photograph ignites negative, yet positive feelings about the condition of the Palestinian people. Said shows that this picture reflects symbols of vulnerability and disarray throughout the Palestinians. We will write a custom essay sample on States by Edward Said specifically for you for only $16.38 $13.9/page Order now We will write a custom essay sample on States by Edward Said specifically for you FOR ONLY $16.38 $13.9/page Hire Writer We will write a custom essay sample on States by Edward Said specifically for you FOR ONLY $16.38 $13.9/page Hire Writer This shabby house, near Senjel, is covered with weeds. It appears to be out of place under the coverage of the trees. Said is very passionate for his own people. He has a great deal of emotional discomfort seeing a photographic display of the dislocation of his own people. I do not know what it feels like to lose my identity and be viewed through a skeptic’s eyes. Although this picture does not appear to incite certain emotions and feelings in myself, it is plausible for Said connect his feelings. Said understands the meaning of displacement with regards to his people’s history. Extra Credit: I can still remember the tragedy of September 11th. I was in second grade. All of the students were immediately sent home or picked up by their parents. I did not understand the images on the news. It almost seemed like a surreal action film. My aunt was on a flight to New York City that day, but luckily she arrived safe. I respect the people and rescue crew involved during September 11th. I think they displayed a deep sense of care for fellow Americans. I hope that the directly affected families have some sense of peace all of these years later.

Sample of Feasibility Sonclusions Essay Example

Sample of Feasibility Sonclusions Essay Example Sample of Feasibility Sonclusions Essay Sample of Feasibility Sonclusions Essay Summary of Conclusion for Feasibility Study of Snack Stand July 15, 2010, 1:11 am Marketing Aspects 1. The Snack stand will be very much positive in offering a lot of services to satisfy customers needs, accept suggestion and criticisms to improve our business 2. Snack stand will utilize with honesty and credibility thru our products and services. 3. Snack stand will be always â€Å"open-minded† to those other competitors and will seek only the best. Technical Aspect 1. The final location of the business will be at the Common Terminal, Balanga City, Bataan. 2. Raw materials will be obtained during its freshness and nearness to the source which is Elizabeth Supermarket in Balanga City itself. 3. The management will provide cleanliness of the stall, especially the food for satisfaction of customers. Management Aspect 1. The best organizational structure to adopt in the same manner communication will be facilitated from the top to bottom and from the bottom to the top. 2. The democratic atmosphere will always prevail in the business to ensure hormones interpersonal relationship between management and personnel. 3. The Snack stand will develop the service activity to satisfy the need of the customer. Socio-Economic Aspect 1. The Snack stand will be very much responsible in promoting environmental, clean air act and proper waste disposal. 2. Taxes assured for the city government. 3. The partner’s will make sure of the observance and God-fearing to all of them. Financial Aspect 1. The amount of fifty thousand pesos (Php50,000. 00) is substantially enough to put up the proposed project Snack stand. 2. Based on the projections as depicted by the financial statements, the proposed project is a kind of lucrative undertaking. . The proponent of the project will be responsible in producing the capital requirement. Prepared by: Arde Reyes Tags: feasibility study snack stand, financial aspect, management aspect, marketing aspect, socio economic aspect, technical aspect Category: Sample Feasibility Study | Comments Off Management Aspect Feasibility Study for Snack Stand June 15, 2010, 8:32 am The c entral idea of management is to make every action or decision help achieve a careful chosen goal. The word management is also used to mean the group of persons called executives who perform management activities. Objectives 1. To keep the subordinates be alert to what is expected to them. 2. To know the duties and responsibilities of each member and personnel. 3. To know different strategies to be able to achieve the company’s goal. Description of Activities 1. DTI Permit Application The business name of GF Snack Stand should be register with the Department of Trade and Industry. It would take only four days to five days before the permit is receive. If there as no other name of its type. Three (3) different name should be apply so when one is approved, so they can use other applied business name (see appendix) 2. Rental Space The project business will be located at Bataan terminal at 2nd floor Ibayo, Balanga City, Bataan. The application will only about three to four weeks before it is approved. 3. Mayor’s Permit The Mayor’s Permit application will acquire the submission of the following: a. SSS Clearance Permit b. Sanitary Permit c. DTI 4. TAN (Tax Account Number) The project business will be registered at the Bureau of Internal Revenue District Office No. (1020) located at Capitol drive, San Jose, Balanga City. The following forms should be accomplished with necessary attachments. BIR FORM No. Attachment Required, Mayor’s Permit and DTI Permit 5. Buying of machineries and equipment Involves the acquisition of the necessary machinery and equipment in the food snack as mentioned in technical aspect. 6. Promotion Includes advertising and personal selling partnership in a variety of promotional activities to inform customer about products and service and to encourage them to buy. 7. Start of Operation After securing all the necessary permits and other needed materials. The said will be now ready to operate. C. Organizational Structure Through GF Snack Stand is just a simple business, the organization structure will have a simple flow. It is not as complicated as big ventures. Over – All manager / Cashier Cook 1, Cook 2 Utility Man 1, Utility Man 2 D. Personnel Structure The GF Snack Stand is required to have the members of personnel and service crew. Staff – Over all Manager – 1 Cashier – 1 Cook – 2 Utility Man – 2 E. Duties and Responsibities 1. Over-all Manager / Cashier Supervise the overall operation of the business Computer the total amount of the purchased item Assist the customers 2. Cook 1 Prepares the necessary ingredients Cooks the items/products 3. Cook 2 Prepares the necessary ingredients Cooks the item/products 4. Utility Man 1 In charge of cleaning the workplace Delivers items within the vicinity In charge of buying raw materials from suppliers In charge of the inventory 5. Utility Man 2 In charge of cleaning the workplace Delivers items within the vicinity In charge of buying raw materials from the suppliers In charge of the inventory Excerpt from Management Project by Arde R. Reyes Ta gs: business requirement, management feasibility, organization feasibility, snack stand management Category: Sample Feasibility Study | Comments Off Business Feasibility Study – Snack Stand June 7, 2010, 2:08 am A. Name and Address of the Business The GF Snack Stand (Good Food Snack Stand) is proposed to be located at the 2nd floor of the Bataan Common Terminal, Ibayo, Balanga City, Bataan. B. Nature Business The GF Snack Stand offers a wide variety of snacks and beverages. It caters the need of the persons in transit and others who are waiting for their ride home in the said common terminal. It also provide hip and soothing music to those who are weary from work and school. The menu mainly consists of chicken, ham, ham and egg and hotdog sandwiches, fishballs, kikiam, squidballs, french fries and juices such as gulaman and pineapple juice. The said snack stand is open Mondays through Sundays from 7:00 AM to 7:00 PM. Management Aspect 1. What are the roles and responsibilities of each personnel? 2. What are the different strategies were going to use in order to cope up with the competition? 3. How can we cope up with the competition? Financial Aspect 1. How much will be the total cost of the project? 2. How much is the contribution of each member? 3. How much profit were going to earn this kind of project? Socio-Economic Aspect 1. How can the business contribute to the reduction of unemployment? 2. How can the business contribute to the community? . How can the business contribute to the economy? Excerpt from Management Project by Arde R. Reyes Tags: business feasibility study, Snack Stand Feasibility study Category: Sample Feasibility Study | Comments Off Sugar Mill Feasibility Study March 2, 2009, 8:04 am Name of the Enterprise This proposed sugar mill shall be called as Sweet Sugar Incorporated, obviously sugar is sw eet and sweet is sugar. That’s why it shall be called as Sweet Sugar Incorporated. Sweet Sugar Incorporated shall have its own plant located in Sitio Maguindong, Luakan, Dinalupihan, Bataan. The site was chosen because its strategic location, where the supplies of public and private services are adequate and labor supply and raw materials are readily available. Sources of Raw Materials The plant shall have its own sugarcane plantation near the mill and the plantation shall be adequate in land area that will produce the needed raw material for sugar. Availability of Transportation The plant site is strategically located in Sitio Maguindong, Luakan, Dinalupihan, Bataan where transportation is not a problem. The plant is readily accessible to the workers. The finished sugar can be readily delivered to the market. Project Long Range Objective The Sweet Sugar Incorporated shall stick to its obligation and responsibility to its consumers of providing and producing the highest quality of sugar. No toxic materials shall be used or if there is, it should be properly disposed. It also respond to the needs of the barangay where it is located in order to help its progress. The Sweet Sugar Incorporated shall be the number one product and supplier of high-grade sugar throughout Luzon and its neighboring provinces, and if expansion is needed, it shall be done without overlooking its primary objectives. Mode of Financing Financing shall come from the shares of the stockholders/owners of the Sweet Sugar Incorporated. If ever the shares can’t cover up the expenses of constructing the plant before its operation, the Sweet Sugar Incorporated shall apply for loans which will give the maximum output for the plant. When business is already in operation, its liabilities and loans shall be paid from the sugar revenue Market Study As Bataan is situated geographically near the center of the Philippines, the finished product can be easily transported to the neighboring provinces in the country. Manila, the leading distribution center in the Philippines will be recipient of greater bulk of the product. Analysis of Market Demand and Supply Sugar is one of the primary commodities of the people, thus it is very important to have big supply that will cover up the big demand for sugar. The establishment of this sugar mill will greatly help our fellow Filipinos and most of all, our economy. This sugar mill will increase the sugar supply in the market, thus lessening our importation of sugar which is more expensive in cost. Market and Marketing Strategy Vigorous effort should be expanded to secure a market before a commitment is made to build a sugar mill if it would be most desirable to have the financial participation of one or more major users who can guarantee the purchase of substantial portion for the procedure production. During the past years, several overtures were made in this direction which revealed the opportunities existing. Scale and Volume The receiving of raw materials supply condition market potential and engineering should be considered. It would have production line which represent 769,434 tons per unit day. The output of the plant will depend on the production conditions. Sugar Marketing Operation The structure of general framework of market situation is already been said of the manner in which selling, shipping, financing and all other commercial aspect of marketing are out inside the general framework. These function rarely been described except by and for the specialist concerned with them. They are the essential link, however, providing the customers with that they want and the sugar industry with their income. The successful selling of the product ultimately determine the prosperity of every one in industry if it s not sold successfully all the efforts of the farmers, millers and readiness with their employees and the most of business which supply and service them will suffer. The final customers are their most important millions of housewives buying sweets or soft drinks not only 4 lbs. of sugar and tin of golden syrup but also the tin of jam. Market Distribution Pricing Pricing s hould follow the established market prices and practices which in turn are determined by the forces of demand and supply, however because of uncertainty of sugar during the start up period, some prices concessions should be made in order to break into market. A suggestion that is to 20% reduction from established market prices be affected on the first year output. Consumer Surveys Everyone is using sugar everyday, but assumed of sugar feeds are centrally as possible within the area of cane fields, as this will facilitate the transportation of cane with less rolling stock and other fixed charges for their department. Moreover, easy cane supply, so necessary for a economical grinding, will secure to the factory. The direction of the prevailing wind and its accessibility to the factory and dwelling should be ascertained to avoid dust, ashes, smoke and odor of refuse going in wrong direction. Healthy surroundings are paramount importance to the employees. Standing and deterioration water must not be allowed near the factory. Technical Study Services Offered: The proposed plant site at Sitio Maguindong, Luakan, Dinalupihan, Bataan offers a plentiful supplies of water and power. The site offers adequate supply of water for growing sugarcane, and power for the production of sugar. It also offers adequate supply of laborers, which is considered more important than all the other factors, especially when skilled and unskilled laborers are required. Labor Skills required The company will hire Filipino larorers in sugar cane manufacturing. Laborers near the company site and more preferable to the employees to insure promptness and can do overtime work when needed Another important reason is that people from nearest place can easily transport with their convenience since the company is small, the working force will be required from town itself or its vicinity. The company on the other hand will give assurance to the workers like a good working condition, facilities for a conductive maintenance of their health incentives and many other benefits required by the labor code, plus benefits given by the company itself. The Project Site Sitio Maguindong, Luakan, Dinalupihan, Bataan was chosen the best region of all sugar plantation in the Philippines due to its abundant supply of labor will not be difficult to achieve as most barrio folk are quite hardworking and industrious. Another reason is because of availability of raw materials and have favorable conditions. The plant would be erected near the national highway which will enable the transportation of finished product to the opposite provinces of course, sugar central will increase their yearly supply of sugar production thus helping the sugar industry. The determination where sugar cane factory is to be located is purely an agricultural one. So far, it is referred t the tract of land which has to be adequate for growing sugar cane fr a period of years and the location where climate condition and rainfall are much that successful crops to be expected. As Bataan is situated geographically near the center of the Philippines, the finished product can be easily transported to the neighboring provinces. Waste Disposal The various waste materials produced by industries maybe classified generally as solids, gaseous or liquid. Solid waste are directly related to a loud pollution gas liquid to air and water pollution, although all of them have combined and interrelated effects on pollution. Methods of Waste Disposal 1. Eliminate of source. The first approach to a waste disposal problem requires a careful attention of the source of pollutants. 2. Recovery of waste products. Before deciding how to discard waste materials, the engineer should always think for recycle, reuse or for sale. 3. Regulate how to fit dilution 4. Divert waste to other points 5. Waste treatment. – A very expensive process the recent encountered by the major cities of the world due to smog problem and the question as due to how to dispose gaseous waste, electrostatic precipitators, aggrometrators, washers and many other kind of equipment have been used to remove atmospheric contaminants. Disposal of solid waste materials on land is always a complicated problem, incineration and burying are possible solution and the best is by recycling. A judicious plant design eliminates a potential hazardous operations should be separated from various plant facilities and sufficient protection is made, possible sources of fire by eliminating all the unnecessary ignition sources such as flame, spark or heated material, welding, smoking, static electricity and the spontaneous combustion of waste materials. Chemicals can cause dangerous burns and accidents are bound to occur rotating sections of equipments should be amply protected to prevent accidents. Management Study For Pre-operating Period: During the pre-operating period, the stockholders are responsible to deal with some government and private agencies to secure the necessary document and deal in financing institution for financial needs of the project. These persons are the one to negotiate for the constructor. The supplier of the materials and by the hired construction firm and the supervision will be integrated with the said contract. Consultant shall be hired also to ensure the safety of the plant and to supervise the installation of the equipment. For Operating Period: During the operating period, the stockholders handled the key position in the company. The business is organized and incorporate with their respective holdings: Board of Directors Chairman of the Board Member Member Member Maintenance and Material Director Company Accountant Sales Director Production Director The company sees to it that hired accountant and supervision directors are all licensed by the professional Regulation Commission (PRC) in their respective professions. All these persons should have at least an experience in their respective jobs. The company accountant is responsible for the books and the preparation of the company book of accounts. He also prepares the payroll and he examines the financial status of the company. The sales director will assists the selling and finding markets for the products. The production director is responsible for the production in order to insure for good productivity and minimize production or manufacturing costs. The maintenance and materials director is responsible for the safety programs and maintenance of the plant. He should set the guidelines and train workers about safety and accidents and be able to continue the flow of the product even machine breakdown occurs, which are hindrance to the company’s re-productivity programs. Financial Study Major Assumption An industry like sugar mill requires a big capital. The stockholders shall provide the needed capital for the establishment of the whole business. Funds shall be given for the purchases of the necessary equipments and necessary materials for the construction of the building and for the purchase of land. In case that there is no sufficient fund, the company shall apply for loan in the bank which gives the lowest interest. During operation, the company shall pay its obligation out its revenues. Equipment cost less than P40,000,000. 00. Building construction (payment for the labors included) costs more than P20,000,000. 00. Land (for the plant site and sugar cane plantation costs P20,000,000. 00. The stockholders shall produce a budget of not less than P80,000,000. 00. Socio-economic Study Taxes and Restricting Law Bataan offers the lowest tax rate for industries like sugar production, and the best of Bataan is, they offer, provide government subsidy and help to the industries located in its territory. Provincial and town legislation are also important. The sweet sugar laws are more stringent in Bataan. Sweet Sugar Incorporated will help boost the economic status of Dinalupihan, Bataan because it will provide a great number of jobs for the unemployed folks in the area, thus, giving them more opportunities in life. Sweet Sugar Incorporated shall pay all its tax obligations on time. This is a partial study of Engr. Eric Lanosa. Tags: Feasibility Study, sugar mill Category: Sample Feasibility Study | Comments Off Some Things to Consider in Establishing a Food Business February 20, 2009, 5:28 am Due to economic crisis, it is hard to decide which business should be started. In order to minimize the risk, a thorough study must be undertaken. Food business is very rewarding since man can give up almost everything except food. Men have to eat in order to live. But of course, you will also to be considered the location, security, market, management, facility, and financial to certain that the business could be carried out profitably. Examples of food business are restaurant, canteen, fast food, bars, coffee shop and many more. Location Location is one of the important things to consider when planning any business. Choose the best place to establish a food business. The location should be accessible to your prospective customer. As much as possible, it should be located near colleges, municipal, church, hospital, public and private offices and residences. Security Safeness of your business should also be considered. The business is secure if it is located around several establishments. Market Know the population of your place in order to know if there are enough people who will patronize your food business. Also, observe your competitors to be able to assume the demands. Food offers must be affordable to the people who live on your community. Facilities Find out the facilities to be used in your business such as the tables, chairs, cooking utensils, etc. Management Identify the personnel to be hired. Financial Estimate the total capital requirements. Forecast the monthly income and expenses of your food business in order to know the potential profits. Consider also the sources of financing. Waste Management Proper disposal of waste should be implemented. What will be the waste disposal method to be adopted. Tags: food business Category: Sample Feasibility Study | Comments Off Example / Sample of a Feasibility Study September 9, 2008, 12:21 am Feasibility Study of Establishing Cindy’s Fast Food Branch Along Plaza of Balanga, Bataan 1. General Objectives 1. 1. Description of the Business Project The proposed business will need a two-storey building in a 2,000 square-meter lot with a parking space at the rear. The customer will drive in the left entrance greeted by the water-sprinkled Indian trees partly shielding the establishment from the fumes coming from the busy street. Embraced by the multi-colored lights, the trees will set the cosmopolitan setting to a rustic atmosphere. The building will be constructed to hide the stockroom complementing the architectural masterpiece. The smoothly cemented exit passing through the well-manicured lawn will draw sights of satisfaction from the customers. The state-of-the-art tables, chairs and utensils will enhance the customers feeling that they are in a five-star hotel. Very affordable, the food will enthrall every customer to come and savor the food over the widely spaced tables on the immaculately marbled floor. The electronically flushing system of the restrooms will motivate the customers to force their friends and relatives to frequent this new Cindy’s Branch at the heart of the Balanga. 1. 2. Project Time Table All minor details considered, the project will start serving the five thousand targeted daily customers within five months. The contractors will complete the fence and the framework of the building in the first month. They will finish the walls and the floors in the second month. They will install the electrical and the air conditioning units in the third month. After the first and second layer coating, they will complete the final painting in the fourth month and finally they will landscape and plant balled-trees in the fifth month. As the project will be in progress, the company will busy the facilities to be used. 1. 3. Management of the Business With three managers alternately scheduled on the eight hour duty to man the 95crew in the 24 hour service, the business will surely satisfy the customers, propelling profit to soar. The personnel will make a customer feel that he is the only one served amidst the queuing multitude. The high wage given by the company and, likewise, the humane treatment of the superiors will inspire the crew to render machine-precise service. 2. Product and Market Aspects 2. 1 Market Outcome A variety of expensive fireworks commence the business to attract the children, students, parents, and professionals. This opening blast will have been advertised a month before. The initial big crowd from the different districts of the province will keep growing to actualize the management’s vision that this Cindy Branch will be the most profitable among the food chains in the City. . 2 Market and Selling Price The customers can order from a variety of choices in the counter staffed with beautiful and handsome ever-smiling crew. The waiters will serve the orders in the well-crafted, smoke free dining areas with both oriental and western motifs to fit their number and their tastes. These areas will enhance customer privacy as the customers enjoy eating while talking about the gossips o f the town, or as they engage in a highly intellectual calisthenics about a hot political issue. The area will also conduce lovers to cement their relationship with their soul-penetrating interlocked gazes that only lovers could fathom, as they savor their food. 3. Technical Aspect 3. 1 Location Factor At the center of Balanga Plaza, this food center will surely draw customers from the cross-section of society. The following factors will back-up the company’s foresight: 3. 1. 1 Topography The 2,000 square-meter lot does not need labeling because the area is already flat and it is located in high location. No matter how strong the typhoon will be, the rains will not flood the area. The customers will not be drawn away from enjoying the services of Cindys. 3. 1. 2 Cost of Land The fertile business venture will cheapen the current P20,000 per square meter piece of land. The forty five million peso worth of property will double after only three years of operation. 3. 1. 3 Security The place will be safe. Secretly installed cameras will monitor every move to ensure the security of the customers. Four security guards simultaneously assigned to the area will guarantee the safety of the clients. This will be backed up by policemen assigned at the outpost nearby. . 2 Size and Layout of the Building To maximize the 40 x 50 meter land area, the engineers will erect the 20 x 30 meter proposed two storey building, leaving five meters at both sides and 18 meters fronting the street. Only two meters will be left at the back of the building. This will ventilate the establishment. 3. 3 Equipment The Bataan Builders will construct the building. This construction company will us e modern building equipment like a cement mixer, caterpillar, automatic digging drill, and other state of the art construction materials. 4. Project Cost 4. The Land and the Building This project will cost about P 45,000,000. 00 which is roughly broken into the following: Cost of 2,000 meter lot – P 40,000,000. 00 Cost of 2 storey building – P 4,000,000. 00 Accessories and Equipments – P 1,000,000. 00 Total Cost – P 45,000,000. 00 The 45 million pesos worth of land is the biggest of the capital investment but it is worth it because unlike the other expenses, the land value will appreciate through the years. The contract with the Bataan Builders for the proposed two-storey building is P 4,000,000. This includes materials and labor. With the five-month paying scheme, Cindy will pay P 800,000 every month until the last month. The food center will need P 1,000,000 for the imported accessories like tables, chairs and other needs. 4. 2 Franchise The food center will pay the current P 1,000,000 Cindy franchise. 4. 3 Sources of Financing The proprietor will put in P 5,000,000. The remaining P 40,000,000 will be borrowed from the bank. 5. Business Operation 5. 1 Revenues With 50 thousand monthly net income target from about five thousand daily customers, the proposed branch projects the following net income by month and years: First month – P 1,500,000. 0 First year – P 18,000,000. 00 Second year – P 36,000,000. 00 Third year – P 54,000,000. 00 Fourth year – P 72,000,000. 00 After four years of operation, this venture will have gained P 11,000,000 as shown in the following computations: Net income in four years – P 72,000,000. 00 Minus the sum of investments – P 61,000,0 00. 00 Difference – P 11,000,000. 00 Loaned money from the bank – P 42,500,000. 00 Interest of loaned money – P 17,000,000. 00 Franchise – P 1,000,000. 00 Maintenance – P 500,000. 00 Total – P 61,000,000. 00 5. 2 Accessories and Equipments Being of high quality, the accessories will still be usable after four years. However, P 500,000 pesos is allotted for maintenance and replacements of damaged property. Summary The figures above prove how financially rewarding this business venture. Because food is a necessity, a venture like this guarantees 99% success. This is especially so if the location is the Plaza like Cindys Plaza. * The feasibility study is a result of the proposed Establishment Cindy’s Fast Food. Tags: Feasibility Study Category: Feasibility Study, Sample Feasibility Study | Comments Off

Risk Management Stratgic Framework Essay Example | Topics and Well Written Essays - 500 words

Risk Management Stratgic Framework - Essay Example Testing effectiveness is also a good method in determining whether or not risk management is creating a higher level of benefit in contrast to the costs of implementation. Performance management should include evaluation and the monitoring of the implementation strategy in order to continue assessing value of the methods of risk management that are being used.1 Question 2: There are a number of responsibilities the public has in terms of risk management. First, it is the responsibility of each individual to make sure that the data is not used responsibly, and that they utilize common sense in protecting their personal identity. Although identity theft is very difficult to prevent, using practical applications of common sense in terms of data supports personal protection, which contributes to overall risk that can come from the use of an individuals identity in order to infiltrate or corrupt data in organizations. Taking immediate action when there has been a clear violation of data is also essential in helping to inform organizations that a breach has occurred. With the help of individuals, organizations and public institutions can help support rapid action against infiltration and corruption which is of benefit to the organization and the individual who participate in the benefits of the organization. Question 3: Risk communications are typically separated with internal and external audiences, each having specific requirements and strategies that must be employed. Two way communications throughout risk management processes provide for the key principles that are intended to be met to be addressed in the management of risk. Transparency is one of the keys to strategizing for risk indication so that everyone who is involved as the essential information in order to perform appropriately and effectively. It is often necessary to communicate with external stakeholders, allowing the public to have appropriate

INDIVIDUAL FASHION MARKETING PLAN Essay Example | Topics and Well Written Essays - 3000 words

INDIVIDUAL FASHION MARKETING PLAN - Essay Example ‘Valentino For All’, the planned brand extension based on diffusion strategy will endeavour to sell luxury products especially female related garments to young consumer segment i.e. teenage girls. The brand extension strategy would make use of social app to communicate with the target consumers and to create greater awareness. The target retail outlets featuring greater share of Valentino brand will enable the company to make its presence within the target masses. Besides, the brand extension will enable Valentino to make its presence more prominent in the competitive market. The prime intention of this report will be towards performing the deep evaluation of a luxury fashionable brand named as ‘Valentino SpA’. This brand has been into fashion business since long and is basically of Italian origin. Since being an Italian fashion brand, all its apparel and fashion products reflect the styling trend and the traditional craftsmanship of Italy. A majority of the products manufactured by this brand belongs to a niche section and are high priced as well (Valentino SpA, 2014). The brand was established by Valentino Garavani in 1960 in Rome, Italy. Since then, the brand has been considerably successful in gaining significant amount of preferences from both male and female customers who like the precision and the styling factor associated with assorted offerings such as clothing, footwear, perfumes, glasses, accessories along with watches. The brand adds a combination of certain important factors which contribute to its success factor. It is a popular brand due to ensuring the offering of a diversified portfolio of products for men and women encompassing clothing, footwear as well as accessories (Valentino SpA, 2014).In the current scenario, the brand has attained significant amount of development under the effective supervision of their Creative Directors Maria Grazia Chiuri and Pierpaolo Piccioli. These creative

Leadership and organizational creativity Essay Example | Topics and Well Written Essays - 250 words

Leadership and organizational creativity - Essay Example Every employee makes part of this family. Getting to work in such an environment inculcates a strong sense of belongingness and high self-esteem in the workers. They can relate to the environment at the workplace just like they can relate to their respective families at home. The employee-centered culture that prevails at the workplace is one of the most important and influential factors that make Spiers-Lopez effective. Employees in such a culture feel empowered and satisfied. Developing such an environment at the workplace is not easy. It takes a lot of dedication, hard work, and most importantly, self-awareness. Awareness of the self and a belief in her personal values has given Spiers-Lopez the confidence that she requires to make informed decisions and have an impact on the team at the workplace so profound that workers feel obliged to let such a culture nurture and

Hong Kongs Economic and Sustainable Growth Policies

Hong Kongs Economic and Sustainable Growth Policies Chief Executive Office of the Chief Executive Tamar Hong Kong In my capacity as the Hong Kong General Chamber of Commerce, I take pressure to write to you express my views on specific economic policies which are the essential features of Hong Kong’s economic development and the sustainable growth. From that perspective, the Hong Kong Government (HKSAR) should concern various factors within the region, in terms of the introduction of junk food tax, human resources and labour force, international trade and technological forces, environment protection and urban renewal planning etc, which are directly affected the social and economic conditions in Hong Kong. This paper addresses to how the HKSAR to reach this position and how it sustains its comparative advantages in conducting meaningful and purposive economic policies in short, medium and long-term over the next five years.. Short-term goal: The introduction of junk food tax The Chamber suggests the introduction of junk food tax on fattening foods or beverages by the HKSAR. According to the 2012 Behavioural Risk Factor Survey (2012), it revealed that 36.6% of the Hong Kong population aged 18 64 was classified as overweight. Therefore, Junk food tax refers to a tax placed upon fattening foods or beverages on attempt to reduce saturated fat consumption, from December 2011 to November 2012 Denmark introduced It is generating support in America, a country with rising obesity rates. http://www.tax-news.com/news/Healthy_Revenues_From_Mexican_Junk_Food_Tax____64781.html http://cheaphealthygood.blogspot.hk/2010/03/junk-food-tax-reader-ideas-opinions-and.html http://www.studymode.com/essays/Junk-Food-Tax-1398531.html Hong Kong has a simple, predictable and low tax system. Medium-term goal:- Human resources and labour force As recently the 2014 Index of Economic Freedom report has mentioned that Hong Kong is rated as the freest economy in the world (Opulentus Overseas Careers Pvt Ltd 2015). The Chamber suggests the adoption of women workers that promotes a balanced and gender equality in our local labour market. Although some commented that the roles of women should be stayed at home to look after the children, it is even less true in the modern society. This is because the aging population and the low fertility rate will give rise to a population deficit, it leads the government encourage more women back to labour market (China Economic Net 2013). As of the latest government edition of â€Å"Women and Men in Hong Kong – key statistics† showed that there was shortage of men in Hong Kong. It represents there are only 864 men for every 1,000 women (The Census and Statistics Department 2014). In order to develop women’s employment opportunities, the HKSAR may consider encouraging women to return to work by providing additional employment training and tools, for example, on-the- job training. Moreover, it would be good to introduce whole-day child care services and after-school care service which could eliminate the concern of working women for the well-being of their families. I believe such approaches are favourable to Hong Kong’s economic growth and beneficial to economic production. This help to increasing the supply of labour and will raise labour productivity in medium-term. Medium-term goal: International trade and technological forces Following to the open door policy, Hong Kong is now a major trade and financial centre where depends heavily on trade. Nevertheless, many countries now regard Hong Kong as a developed economy and exclude its products from preferential export treatment, such as subject to quota requirements and suffer higher tariff rates (Augustine 2003, pp. 93-5). To tackle the trade restriction, the HKSAR should appeal to the World Trade Organization through international negotiation with foreign countries which able to promote the growth of industries and conduct the international trade relationships. On the other hand, we recognise that developing a global network may also create a new global economy powered. With the rapid shopping online nowadays, the use and integration of information and communication technologies in business has revolutionized relationships within organizations and those between individuals and organizations (Totonchi Kakamanshadi 2011, p. 270). Therefore, the HKSAR should bring about investment in technology innovation to enable cross-border trading activity without the constraints of business location, scale and time zone. It probably would imitate the shopping engine, like Tobo in China which has increased its e-commerce offerings, makes online shopping easier and more efficient. This strategy allows Hong Kong to maintain substantial economy growth with the increased logistics demand and will bring in new revenue to the industry. Long-term goal:- Environment protection Increasingly, global warning, holes in the ozone layer and population growth etc, are some of the major problems facing in our city. These caused adverse effects of our health and the image of the city. Responses to these problems seem likely to be driven by government. It is suggested that the HKSAR re-examine our environmental protection policies with the implementation of new sustainability policies to ensure Hong Kong people are in full awareness of environment protection and conservation. For example, a move by government to encourage the use of alternative sources of energy such as solar energy that is advocated energy saving living. We are also highly recommended the HKSAR tend to plant as much as trees not only in our country parks, but also along the roadside and around the schools. This is because tree plantation in our community is to help offset the emission of carbon dioxide and stop the global warming. As a result, the standard of living will be increased and we will become healthier that enriched the life of Hong Kong people to future generation. Our economy will also grow and benefit from spending less on healthcare and increasing of the labour productivity. Long-term goal:- Urban renewal planning It is no doubt that the land in Hong Kong is always a highly scare resource. In view of this, the HKSAR should take an active role in maximum the utilization of the scare urban land. The Chamber suggests that undertaking high-density development as well as builds more public rental housing onto the housing market in the next five years. For example, the HKSAR could probably redevelop the old public housing estates to improve the quality of urban living and increase in housing supply. Effective land uses from high –density living will provide support to the HKSAR’s long-term housing policy. Subject to the high-density building development, it is not only helps provide scale economies, but also allows Hong Kong residents more likely to be affordable. These are also ideal help to reduce the pressure to develop open spaces and release more lands for social infrastructure and services. In the longer-term perspective, it is therefore to support economic stability and prosperity which is to meet the market demand. http://www.medwelljournals.com/fulltext/?doi=pjssci.2010.244.253 Many countries embarked as rebuilding efforts, characterized by demolition of old dilapidated areas, large-scale clearance of city slums and construction of modern high-rises after the war. Large-scale redevelopment created many social problemsand encouraged many city planners and scholars to question its effects and functionalities. Indeed, large scale renewal and redevelopment efforts have been criticized for neglecting the complexities of the urban fabric; it is not only uneconomical but also damages the city’s heritage and degrades various socio-environmental qualities. http://ucsfhr.ucsf.edu/index.php/pubs/hrguidearticle/chapter-12-managing-diversity-in-the-workplace/ http://en.ce.cn/subject/exclusive/201311/07/t20131107_1721448.shtml it would be good to introduce more specific incentives for women in the older age groups to upgrade their skills and knowledge Our economy will grow and benefit from these changing demographics if businesses commit toOpulentus Overseas Careers Pvt Ltd The Government welcomes more concerted efforts to build a more caring, compassionate and harmonious society. It is therefore most encouraging to note the growing interest of the business sector and the more affluent members of our community in poverty alleviation. We stand ready to work hand in hand with all sectors to improve the well-being of the disadvantaged and light up their lives with hope and dignity. Reference List A. J. Youngson. 2014, Hong Kong: Economic Growth and Policy, Journal of Asian Studies, vol. 43, no.4, pp. 754-755. Augustine W.S. Li 2003, Introductory Economics 4, Longman Hong Kong Education., Hong Kong. China Economic Net 2013, HK seeks women workers as aging population looms, viewed 21 January 2015, http://en.ce.cn/subject/exclusive/201311/07/t20131107_1721448.shtml>. Christopher, S 2011, Hong Kong’s Expanding Obesity Problem, Journal of the Wall Street, viewed 24 January 2015, http://blogs.wsj.com/hong-kong/2011/01/10/hong-kongs-expanding-obesity-problem/>. Edward. NG 2010, Designing high-density cities, Earthscan, New York. Fifarek, B. Veloso, F. 2010, Offshoring and the global geography of innovation, Journal of Economic Geography, vol. 10, pp. 559-78. Opulentus Overseas Careers Pvt Ltd 2015, The Freest Economy In The World Hong Kong, viewed 21 January 2015, http://www.opulentuz.com/immigration/news-details/the-freest-economy-in-the-world-hong-kong/2437>. The Census and Statistics Department 2014, Women and Men in Hong Kong – key statistics, 2014 edition, Hong Kong. The Department of Health 2012, Obesity, viewed 23 January 2015, http://www.chp.gov.hk/en/content/9/25/8802.html>. Totonchi, J. Kakamanshadi, G. 2011, Globalisation and e-commerce, 2nd International Conference on Networking and Information Technology, IACSIT Press, Singapore.

Thousand Acres Essay -- essays research papers

A Thousand Acres, by Jane Smiley, is a story of incest, ignorance, and the imperialistic voice of the almighty man. Ignorance of being lead by a man, particular views of Rose and Ginny, and domesticated to believe that "When we are good girls and accept our circumstances, we're glad about it. . .When we are bad girls, it drives us crazy" (99). The imperialistic voice usually comes from the omnipotent Larry Cook, Rose, Ginny, and Caroline’s father. And the incestuous relations only entangle this dysfunctional family. The eldest daughter, Ginny, is the most loyal and idolizes her father. The second eldest daughter, Rose, is linked to her father through Ginny, who keeps her from losing faith in him. Rose questions whether the loyalty that Ginny shows her father makes her obedient or if her reluctance to judge him proves her ignorance. Rose has two daughters, Pammy and Linda, who are also first hand witnesses to the episodes of the Cook family trauma, but remain dormant to what goes on around them. Caroline, the youngest daughter has left the one thousand acres of land they grew up on to become a lawyer. Caroline is married to Frank Ras, whom also is a lawyer and they do not have any children. The book is narrated from Ginny’s viewpoint. Ginny is married to Ty and they don’t have any children, but Ginny secretively keeps trying. Ginny also has an extramarital affair with Jess Clark, son of Harold Clark the neighbor and best friend of Larry Cook. Jess has just returned to Zebulon County from the food corp. Given the basic character summary, one of the themes or recurrent ideas that was present throughout the whole book was domination. This domination concept was usually brought to life through the character, Larry Cook, over issues like farming, food, appearance or anything else that didn’t sit well with his expectations in life. Being that domination is not something tangible, conflicts such as the above mentioned were used to develop the theme idea into a concrete representation and also illustrate the effects that the domination theme had on the women of Zebulon County. The whole farming conflict begins when Larry Cook impulsively decides to distribute his one thousand acres of farmland to his three daughters and Caroline, the youngest daughter... ... with his opinions. In this male-dominated culture, it’s as if women are material possessions and the place of women is dependent on men. And at first, the women accepted this. Ginny remarks, "of course it was silly to talk about my point of view. When my father asserted his point of view, mine vanished" (176). And so did her dignity. Larry Cook, Farmer of the Year! In conclusion, the above conflicts portray the domination overtones and the effect that the domination had on the women. Larry Cook seems to be a jack of all trades. He is portrayed as being a god, a businessman, and a farmer. But Larry lacks when it comes to the being, Larry Cook, the father. He is so strict about having things done a certain way with little variations that it blinds him to the wants and needs of those around him. Initially the novel, Ginny suppresses her voice and remained an obedient figure. She has been cultured to believe that a woman has to rely upon the masculine authority figure. As Ginny’s character develops, she begins to break through the mental chains of masculine dependency and start a new life for herself without regret.

G4S Competitive Forces

According to â€Å"Management, 10th Edition† and Michael Porter’s model, when speaking in terms of competitive forces it should be viewed in five different areas; the first being the threat of new entrants. As for a company such as G4S Secure Solutions, the threat from new companies are pretty much non-existent. It being the top security firm worldwide, its threats comes from its larger competitors that are pretty much on their level and well established. Start-up security companies are challenged by the behemoths that dominate the market which are able to overshadow them by offering one stop shopping for multiple security needs.Also the smaller companies have often been taken over by the larger companies. According to Security Guard Magazine (www. securitymagazine. com), two in 10 of guarding firms say they purchased another firm in 2002, while 10 percent say they completed the purchase of another firm in the first half of last year. New companies do not appear to pose a threat to G4S Secure Solutions as they are well established and far ahead of its established competitors. The second of the competitive forces having an impact on the company is its competitive rivalries. The biggest rivalry to G4S Secure Solutions is Securitas Security Services.These two companies offer the same services and both also operate overseas which allows them to compete for business in the same markets. They often end up bidding against each other for contracts vying to provide the exact service for the least amount of dollars. Securitas Security Services entered the U. S. market in 1999 by acquiring Pinkerton and became the largest security firm in the world; they were already the leading protective service company in Europe. They have acquired numerous security firms; in one year alone they had acquired four firms.With them continuing to grow in assets and size, they continue to prove themselves as the most formidable rivalry in this market. The threat of substitute products also has an affect on the company. The consumers are always looking for a better or less costly product that could provide the same service. Businesses are also looking for the next big thing to revolutionize the market. There are some substitute products that have an impact on the company such as guard dogs, security cameras, rolling shutters, security tags, and added lighting.Guard dogs and rolling shutters eliminate the need for security officers altogether and they are a more cost efficient way to provide security. Department stores are now using security tags instead of officers; if someone leaves the store without the tag being removed it will activate an alarm at the door. Some people have the belief that just adding extra lighting to an area ensuring that it is well-lit can also deter burglars or criminals. Depending on the level of security needed, all of these products can be used as a substitute product.As a competitive force, the buyer does not influence what th e company sells, but the company has power over the buyer. This is a well established company that is known to provide top notch service; which also happens to be the top security firm. They do not have to continually lower their fees in order to attract customers. Their reputation is outstanding and many times, consumers may be willing to pay the extra dollars because they know they will be getting premium service with this company.When it comes to G4S Secure Solutions the power is in the hands of the supplier; they have their reputation to go own as they easily have the ability to influence potential buyers. Their resume speaks for itself, the largest security firm, servicing more places worldwide than any other firm, possibly the best trained personnel of security firms, and more trusted by the most prestigious companies than any other security firm. With a background as such, G4S Secure Solutions definitely has the competitive edge when it comes to luring coustomers.

Antibiotic Resistance In Bacteria Essays - Pharmaceuticals Policy

Antibiotic Resistance In Bacteria Essays - Pharmaceuticals Policy Antibiotic Resistance In Bacteria For about 50 years, antibiotics have been the answer to many bacterial infections. Antibiotics are chemical substances that are secreted by living things. Doctors prescribed these medicines to cure many diseases. During World War II, it treated one of the biggest killers during wartime - infected wounds. It was the beginning of the antibiotic era. But just when antibiotics were being mass produced, bacteria started to evolve and became resistant to these medicines. Antibiotic resistance can be the result of different things. One cause of resistance could be drug abuse. There are people who believe that when they get sick, antibiotics are the answer. The more times you use a drug, the more it will decrease the effect it has on you. That is because the bacteria has found a way to avoid the effects of that antibiotic. Another cause of resistance is the improper use of drugs. When patients feel that the symptoms of their disease have improved, they often stop taking the drug. Just because the symptoms have disappeared it does not mean the disease has gone away. Prescribed drugs should be taken until all the medicine is gone so the disease is completely finished. If it is not, then this will just give the bacteria some time to find a way to avoid the effects of the drug. One antibiotic that will always have a long lasting effect in history is penicillin. This was the first antibiotic ever to be discovered. Alexander Fleming was the person responsible for the discovery in 1928. In his laboratory, he noticed that in some of his bacteria colonies, that he was growing, were some clear spots. He realized that something had killed the bacteria in these clear spots, which ended up to be a fungus growth. He then discovered that inside this mold was a substance that killed bacteria. It was the antibiotic, penicillin. Penicillin became the most powerful germ-killer known at that time. Antibiotics kill disease-causing bacteria by interfering with their processes. Penicillin kills bacteria by attaching to their cell walls. Then it destroys part of the wall. The cell wall breaks apart and bacteria dies. After four years, when drug companies started to mass produce penicillin, in 1943, the first signs of penicillin-resistant bacteria started to show up. The first bacteria that fought penicillin was called Staphylococcus aureus. This bug is usually harmless but can cause an illness such as pneumonia. In 1967, another penicillin-resistant bacteria formed. It was called pneumococcus and it broke out in a small village in Papua New Guinea. Other penicillin resistant bacteria that formed are Enterococcus faecium and a new strain of gonorrhea. Antibiotic resistance can occur by a mutation of DNA in bacteria or DNA acquired from another bacteria that is drug-resistant through transformation. Penicillin-resistant bacteria can alter their cell walls so penicillin can not attach to it. The bacteria can also produce different enzymes that can take apart the antibiotic. Since antibiotics became so prosperous, all other strategies to fight bacterial diseases were put aside. Now since the effects of antibiotics are decreasing and antibiotic resistance is increasing, new research on how to battle bacteria is starting. Antibiotic resistance spreads fast but efforts are being made to slow it. Improving infection control, discovering new antibiotics, and taking drugs more appropriately are ways to prevent resistant bacteria from spreading. In developing nations, approaches are being made to control infections such as hand washing by health care people, and identifying drug resistant infections quickly to keep them away from others. The World Health Organization has began a global computer program that reports any outbreaks of drug-resistant bacterial infections. In the early 1900's, the discovery of penicillin began the antibiotic era. People thought they have finally won the battle with bacteria. But now since antibiotic resistance is increasing rapidly, new strategies must be developed to destroy these microbes. To many scientists the antibiotic era is over Bibliography Bylinsky, Gene. Sept. 5,1995. The new fight against killer microbes. Fortune. p. 74-76. Dixon, Bernard. March 17,1995. Return of the killer bugs. New Statesman & Society. p. 29-32. Levy, Stuart B. Jan. 15,1995. Dawn of the post-antibiotic era? Patient Care. p. 84-86. Lewis, Ricki. Sept. 1995. The rise of antibiotic-resistant infections. FDA Consumer. p. 11-15. Miller, Julie Ann. June 1995. Preparing for the postantibiotic era. BioScience. p. 384-392. an excellent news article summary, got me a 100, by strife007

25 Names of Fabrics, Wools, and Leathers Derived from Place Names

25 Names of Fabrics, Wools, and Leathers Derived from Place Names 25 Names of Fabrics, Wools, and Leathers Derived from Place Names 25 Names of Fabrics, Wools, and Leathers Derived from Place Names By Mark Nichol This post lists and defines terms for apparel materials that have in common that the terms are derived from place names. 1. angora: a type of wool from Angora rabbits, which originated near Ankara (previously Angora), Turkey 2. Bedford cord: a corduroy-like fabric, named after Bedford, England, or New Bedford, Massachusetts 3. calico: a type of cloth originally from Calicut, India 4. cambric: a type of cloth originally from Cambrai, France 5. cashmere: a type of wool and a woolen fabric from Kashmir goats, which come from the Kashmir region of India 6. chino cloth: a cloth originating in China (the name is Spanish for â€Å"Chinese†) 7. Cordovan leather: a type of shoe leather first produced in Cordoba, Spain 8. damask: a type of fabric named after Damascus, Syria 9. denim: a type of fabric originally called serge de Nà ®mes, or â€Å"serge of Nà ®mes,† after Nà ®mes, a town in France 10. dungaree: a type of denim cloth originating in DongrÄ «, India; pants or overalls made from this fabric are called dungarees 11. duffel: a cloth first made in Duffel, Belgium 12. Harris tweed: a type of handwoven tweed cloth originating on the island of Lewis and Harris and adjacent islands in Scotland (the name of the cloth type tweed is coincidental with the name of the river Tweed) 13. Holland (or Holland cloth): a type of linen originally made in various parts of Europe, including the province of Holland in the Netherlands 14. jaconet: a fabric originally from Puri, India (the word is derived from the name of the city’s Jagannath Temple) 15. jean: a type of fabric originating in Genoa, Italy 16. jersey: a type of knit fabric originating on the island of Jersey, next to France (but a dependency of the United Kingdom) 17. Mackinaw cloth: a woolen cloth used for thick, warm jackets (called Mackinaws or Macs) originally favored by lumberjacks and then hunters and fishermen in the Mackinac (or Mackinaw) region of Michigan 18. madras: a lightweight cloth originally from Madras, India (now called Chennai) 19. muslin: a lightweight fabric originally from Mosul, Iraq 20. Morocco leather: a type of leather originally from Moroccan goats 21. nankeen: a type of fabric originating in Nanjing, China (previously called Nanking or Nankin); also refers to pants made of this material, as well as the pale buff or yellow color of the fabric, a type of porcelain originating in the city, and a type of lace (often called nankins) and part of the name of numerous animals and plants featuring this color 22. osnaburg: a coarse cloth originally made in Osnabrà ¼ck, Germany 23. suede: a type of leather made from the underside of animal skins, originally referenced in the French phrase gants de Suà ¨de (â€Å"gloves from Sweden†); similar-looking fabrics are referred to as â€Å"sueded silk† and so on 24. tulle: a type of fabric originating in Tulle, France 25. worsted: a type of wool whose name is derived from that of Worstead, one of the villages from which it originated; also, the name of a type of yarn and a category of yarn weight Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Vocabulary category, check our popular posts, or choose a related post below:Regarding Re:Proved vs. ProvenEnglish Grammar 101: Prepositions

Public Administration in Northern Ireland Essay

Public Administration in Northern Ireland - Essay Example (2) A brief time line of RPA 2002 RPA was initiated 2003 RPA consultation was launched 2004 The consultation finished 2005 In august, second stage started, in September second stage closes, in November lord rooker denounced results of RPA process. 2006 June 2006 a briefing by NICVA [Northern Ireland Council for Voluntary Action], In December Gavin Boyd appointed Chief Executive Designate of Education and Skills Authority. (3) 2007 In July a review of local government's issues of RPA was launched by environmental minister. 2008 13th march Forster, environmental minister, explained the possible future shape by creating more 11 local governments keeping the already existing 26. (2) Why is it so late to implement RPA Considering the above-stated facts, one can understand the huge task which was initiated in 2002 and termed as RPA [review of public administration] is far better fitted in theory than in practice. It is almost impossible to meet the time frame and maintain harmony with all these councils, local governments and with the departments keeping the system of checks balances intact. Some factors are highlighted here. Timeframe which is not enough for RPA Possible lack of Co-ordination between different departments. Weak legislative support is another reason A must need of agreed framework of execution of RPA. The sharing of responsibilities between local councils and community and organizations within the RPA boundary is not that easy task. The separation of tasks and efficiency checking program is still unclear by the departments causing further delay. Conclusion Though RPA offers a good opportunity for local governments and organizations to propagate in public sectors, yet, the...(1) All these reforms are to be implemented through councils, community planning, primary care-led commission groups and various other tools to help public administration working in practise and not just theory for the welfare of the people. But the provided timeframe for such huge alteration of administrational structure and making it efficient is clearly too short for undergo these changes practically. Considering the above-stated facts, one can understand the huge task which was initiated in 2002 and termed as RPA [review of public administration] is far better fitted in theory than in practice. It is almost impossible to meet the time frame and maintain harmony with all these councils, local governments and with the departments keeping the system of checks balances intact. Some factors are highlighted here. Though RPA offers a good opportunity for local governments and organizations to propagate in public sectors, yet, the uncertainty and confusion it brought over years can not be ignored and immediate steps must be taken to make the slow process fast. The review of public administration in Northern Ireland, initiated in 2002, aimed at particular and specified targets achievement factor to enhance efficiency and improvement in public sector involving Health, Education, Finances, legislative, executive co-ordination and

Assignment on Microeconomics 5 questions (350 words to each question) Essay

Assignment on Microeconomics 5 questions (350 words to each question) - Essay Example Cost when unoccupied $76.00, Minus dog care $8.00, Minus security firm $10.00 the balance is $58.00. We also consider depreciation that occurs in excess when someone is living in the house, the excess depreciation is $5, so we add the balance above which gives us $58 plus $5 equals $63. On the gardener's services, because the person renting the house takes care of the gardening services his cost of leaving his house unoccupied reduces by $10 therefore we get $63 minus $10 we get $53. The surgeon should reduce his tent by both the value of dog care and need for a security firm because this are taken care by the person living in the house so our value will be 53-18=35. Therefore the minimum amount the surgeon should accept to receive, as rent should be $35. Substitute goods are products that are similar in that they satisfy the same want, if one's good is not available one can substitute it with another example butter and margarine that are consumed with bread. Butter and margarine can be substitutes of one another. Perfect competitive market is a theoretical market structures in which there are many buyers and sellers with no individual power to influence market price. Prices are determined by demand and supplies in the market assumptions of a perfect competitive market are: Many buyers and sellers, Perfect mobility of factors of production, perfect knowledge, homogenous products, absence of externalities. (Hardwick, Khan & Langmead, p 91, 1997). The analysis of equilibrium price and quantity was by Alfred Marshall (1842-1924). He analyzed the demand curve and the supply curve and stated that where the two curves intersect, they give us the equilibrium price and quantity in the market. (Hardwick, Khan & Langmead, 1997). Qo is the equilibrium Quantity Po is the equilibrium price a) Equilibrium price of butter has increased and that the equilibrium quantity of bread has increased. Possible explanations are: I. Price of milk has decreased - If the price of milk decreases then we expect the price of butter to go down. This is explained by the fact that in production of butter, milk is the key input in the process. Therefore, a decrease in the price of butter cannot explain an increase in price of butter. II. Price of flour has decreased - If price of flour decreases we expect price of bread to go down because flour is the key input in production of bread. If price of bread decreases we expect an increase in the quantity demanded of bread. Therefore this explains the increase in equilibrium quantity of bread. On butter - as the bread demanded increases and having in mind that bread and butter are complementary goods. We expect the price of butter to go up also due to increased demand. Demand and Supply Curve for Bread Price Po P1 SSo 0 Quantity The decrease in price of flour causes the supply curve of bread to shift downwards from SSo to SS1 . our

Memory, Thinking, and Intelligence Essay Example | Topics and Well Written Essays - 500 words

Memory, Thinking, and Intelligence - Essay Example These are analytical, experiential and practical intelligence. The above listed behaviours for both academic and everyday intelligence fit into Sternberg's theory. Academic intelligence corresponds with both experiential and componential intelligence, as defined by Sternberg. Experiential intelligence essentially refers to the capacity to comprehend tasks, even novel ones, and execute them efficiently. In relation to academic intelligence, it references the capacity to assimilate knowledge, comprehend abstract terms and apply that knowledge, including the translation of the abstract into the practical. As regards componential intelligence, it essentially refers to problem-solving which, in itself, is predicated on the intellectual analysis of the problem and the selection of the optimal solution. In others words, insofar as the behaviours listed for academic intelligence ultimately derive from the capacity to assimilate and apply new knowledge, they correspond to Sternberg's theory of intelligence. As regards the behaviours listed for everyday intelligence, they correspond with Sternberg's experiential and practical intelligence.

The challenges of globalisation Essay Example for Free

The challenges of globalisation Essay Next offers an international delivery service to all there online customers this could be challenging for next to because if they give international customers an estimated delivery of their products they are completely relying on their curriers, and if the product does not arrive on the day that next said It would then next could get a bad reputation and bad reviews this will have a negative impact on the company and will discourage customers from buying online this means that next will see a decrease in sales. Availability Since Next went global there has been a huge increase in demand for next products this makes it hard for next to have all of their products available to everyone all the time, in fact it would be impossible so certain people will be forced to wait a long time for the product they want. However as long as next can make their products available to the majority of customers then they will not lose customers. Laws and regulations Laws and regulations would prevent Next from sending items such as lighters, sharp objects and electrical this could narrow the products that next have available for sale in other countries. Other laws that next may face are the import tax that they will have to pay on importing goods to and from countries. Language Language could be a barrier for some companies that want to globalise themselves, however for next a company which is such a big concern, their websites are available in every language that they sell in, this makes it easy for customers from abroad to purchase whatever they please from the next website. Customs Customs can be huge problems for companies. it could be problem for Next because when shipping long distance of the items could be delayed and this could impact the customers delivery date, this could give Next a bad reputation and have an impact on sales. Tax Tax will have a huge effect on next because every country has different tax rates the UK tax rate for value added tax is 20% and Spain’s 36.3% this means it is more expensive for consumers in spin to purchase next goods. Currency payments/security of payments Cultural sensitivity Next have customers all over the world, this could be a problem to Next because some of the items that they sell in UK stores may not be available in countries such as Dubai. Why is this? Certain laws and regulation will deter Next from selling goods that they know are much less likely to sell in certain geographic locations such as Dubai. In short Dubai’s culture frowns upon revealing clothes for example, women’s dresses with low necklines which would be perfectly acceptable in the UK, would be going against culture and even breaking laws in Dubai so it would make no sense for next to mass advertise this product however in the UK the dress could be a huge success and make next lots of money. In contrast there will be a minority of people that want the dress in foreign countries this can create a dilemma for next because the majority of shoppers worldwide would admit to switching shop if they cannot find the product they want or need. Keeping up with trends in other countries It is a challenge to keep up with trends in one country, however next has to keep up trends in over 70 countries, it is challenging because trends can change on a monthly or even weekly basis, so next cannot simply sell one range of clothing in every country because every country will have different demands so they must tailor their stock to there diffrerent target markets abroad.

Ir Spectral Analysis Of Oxovanadium Acetylacetone Biology Essay

Ir Spectral Analysis Of Oxovanadium Acetylacetone Biology Essay Complex will have ligand that will form coordination bond to the metal center by donating lone pairs of electrons to the empty d-orbital of the metal which is similar to the Lewis acid-base reaction. In this experiment, Acetylacetone and pyridine is the ligand will act as Lewis base and will be coordinated to the metal center of Vanadium, V, which is the Lewis acid. Acetylacetone is a ÃŽ ²-diketone that contains two alpha hydrogen atoms adjacent to the two carbonyl groups. As carbonyl-group is electron withdrawing group, these two carbonyl functional group will create an inductive effect which cause the alpha hydrogen to be more acidic and be easily deprotonated. Resonance stability of delocalising the anion formed from the deprotonation under basic condition also increases the probability of the deprotonation as shown in Figure 1: Figure 1: Mechanism of the deprotonation and delocalization of the alpha hydrogen Acetylacetone exist in both keto and enol isomer form as shown in Figure 2: Figure 2: Keto-enol tautomerisation of the Acetylacetone The enolate anion is able to act as a bidentate ligand as it can chelate onto the oxovanadium metal ion with the two oxygen atoms as the binding sites to form the VO(acac)2 complexes. Two acetylacetonate ligands are able to bind to the oxovanadium metal and form a square pyramidal complex. Addition of the pyridine compound will form an octahedral geometry complex. These can be further proven using IR spectroscopy where the different strengths, lengths and nature as according to Hookes law, IR absorption spectra is able to be unique for each complex. Experimental Procedure Preparation of VO(acac)2 The preparation of VO(acac)2 started with 5ml of concentrated sulfuric acid (H2SO4) slowly added to 5 ml of deionized water in a 50 ml round-bottomed flask. Then, 18 ml of ethanol and followed by 2 g of vanadium pentaoxide (V2O5) was added into the round bottom flask. The solution was refluxed in an oil bath for an hour. The mixture was then cooled and filtered using cotton wool. Subsequently, 6 ml of Acetylacetone was added drop wise to the filtrate. The reaction mixture was carefully added portion by portion to the solution that contained 7.4g of Na2CO3 in 120 ml of deionsed water in a 500 ml conical flask. The mixture was then cooled in ice water and filtered to obtain the dark green product. Product was dried under IR lamp. The product was weighted and percentage yield was calculated. Preparation of VO (acac)2py The VO(acac)2py was prepared first by dissolving 0.5 g of the VO(acac)2 products obtained in 20 ml of ethanol in a 50ml of round bottom flask. Then, the mixture was refluxed vigorously with 2 ml of pyridine for one hour which was then concentrated using rotary evaporator. Crystal of crude VO(acac)2py formed upon cooling in ice water which was then filtered and wash with 5 ml of ether. Product was dried under IR lamp. The crude dry product was weighted and percentage yield was calculated. The IR spectrum of product was then determined. Data Treatment and Analysis Calculation of Percentage Yield of VO(acac)2 The percentage yield was calculated using the following equation: V2O5 + 4H+ Æ’Â   2(VO)2+ + 2H2O + O2 -Reaction 1 2(VO)2+ + 2 acacH Æ’Â   2H+ + VO(acac)2 Reaction 2 Mole of H2SO4 used = Amount of H+ present = 0.0938 mol x 2 = 0.1876 mol Mole of acac used = Mole of V2O5 used = (limiting agent) The ratio of V2O5 and VO2+ is 1:2, Mole of VO2+ used = 0.0111 mols x 2 = 0.0222 mols As ratio of VO2+ and VO(acac)2 is 1:1, then theoretical mole of VO(acac)2 = 0.0222 mols Theoretical mass of VO(acac)2 = mole of VO(acac)2 x molar mass of VO(acac)2 = 0.0222 mols X 265.16 g/mol = 5.890 g Percentage yield of VO(acac)2 = Calculation of Percentage Yield of VO(acac)2py Mole of pyridine used = Mole of VO(acac)2 used = (limiting agent) VO(acac)2 is the limiting agent. The ratio of VO(acac)2 and VO(acac)2py is 1:1. Mole of VO(acac)2py = 0.00194 mols Hence, theoretical mass of VO(acac)2py = mole of VO(acac)2py X molar mass of VO(acac)2py = 0.00194 mols x 344.26 g/mol = 0.667 g Percentage of VO(acac)2py yield = Infra-red Spectroscopy Table 1: Summarized Data from IR spectrum of VO(acac)2py Important peaks observed in the spectrum of VO(acac)2 /cm-1 Important peaks observed in the spectrum of VO(acac)2py /cm-1 997.7 998.04 966.04 3449.72 Discussion Geometry of VO(acac)2 and VO(acac)2py Vanadium [IV] metal exists as vanadyl, VO2+ in aqueous solution. Before the reaction of the VO2+ with the acetylacetonate, VO2+ is coordinated to five water molecules and existed as octahedral geometry. However, acetylacetonate is a stronger ligand that displaces the water molecules. Since Vanadium is bonded to oxygen with a V=O bond, only 2 acetylacetonate will only be able to form coordinate bond with the vanadium central metal ion to form the VO(acac)2 complex with a square pyramidal geometry as shown in Figure 3. Figure 3: Reaction diagram of the coordination geometry of VO(acac)2 and VO(acac)2py The geometry of this complex is in the square pyramidal geometry instead of the trigonal pyramidal geometry is due to the steric effect caused by the acetylacetonate ligands. The geometry of the square pyramidal is to reduce the steric repulsion to the minimum with the optimal distance apart of the two ligands. Also, from Figure 3, it can be seen that there is a vacant coordination site on the principle z-axis available which allow another more coordination site if there is the presence of strong ligand such as pyridine in this experiment. Therefore, complexation occurred between the pyridine molecules and the VO(acac)2 where nitrogen lone pair in the pyridine molecules act as a Ï€- donor-ligand and strong Lewis base that donate the lone pair of electron to the VO(acac)2 complexes at the vacant coordination site. With the new VO(acac)2py complex formed having a distorted octahedral geometry due to the unequal bond length between the V=O bond and the V=N bond at the axial position of the vanadium metal centre which lead to asymmetry. Also, the octahedral geometry of the VO(acac)2py is a 6-coordinate complex that is of high thermodynamic stability. Shifting of the V=O stretching band The complex of the VO(acac)2 has an oxidation complex of +4 which the vanadium(IV) ion exists as a d1. Using the Crystal Field Theory, there is electronic repulsion between the electrons of the acac ligands and the electron on the vanadium metal ion which causes the initially degenerate 5 d-orbitals of vanadium metal ion to split into two different levels. The level with the lower energy has a t2g symmetry and consists of the dxy, dxz, and dyz atomic orbitals. The level with the higher energy has eg symmetry and consists of the dx2-y2 and dx2 orbitals. The difference between the energy levels is the ligand field splitting parameter, à ¢Ã‹â€ Ã¢â‚¬  o. In the octahedral geometry, eg orbitals are on the axial direction and are the most affected by the electrostatic repulsion which destabilize the orbitals and excite them to higher energy level. The t2g orbital is not on the axial position and thus, not much affected by repulsion and thus, stabilized and move to lower energy as shown in Figure 4: eg orbital à ¢Ã‹â€ Ã¢â‚¬  0 Energy dx2-y2 dx2 dxy dxz dyz t2g orbital Figure 4: Molecular diagram illustration of Crystal Field Theory As mentioned in the previous paragraph, the pyridine is a Ï€ donor ligand that binds to the VO(acac)2 complex at the vacant site at the axial position of the vanadium(IV) ion. The addition of the pyridine to the complex reduces à ¢Ã‹â€ Ã¢â‚¬  0 which this reduction of the splitting parameter was observed using the comparison of the IR spectrum of the VO(acac)2 and VO(acac)2py. From the spectrum found in Appendix 2, the spectrum of the VO(acac)2py complex can be seen that the V=O stretching frequency of VO(acac)2py complex is 32 cm-1 lower than the VO(acac)2 complex when the V=O stretching frequency decrease from 998.04 cm-1 to 966.04 cm-1. These reduces of the stretching frequency is proportional to the stretching energy of the V=O bond of the complex. The addition of the pyridine will result in the reduction of the stretching energy of the V=O bond. This shows that the V=O bond of the VO(acac)2py is destabilized upon the addition of pyridine to VO(acac)2. This can be shown using Hookes Law as shown: where v is the stretching frequency in cm-1, k is the force constant, ÃŽ ¼ is the reduced mass. The binding of the pyridine has decrease the force constant and the lone pair of the pyridine ligand is electron-donating which increases the mass of vanadium ion that result in larger reduced mass, ÃŽ ¼, which according to the Hookes law, result in lower stretching frequency wavenumber. The wave number is proportional to the amount of energy that is needed for transition where it highly depends on the ligand field splitting parameter. The shifting of the stretching frequency indicate that the ligand field splitting parameter has decreased in magnitude which the addition of the pyridine ligand has caused destabilization of VO(acac)2py complex. Similarly, the lone pair of electrons of the nitrogen in pyridine is added onto the anti-bonding of the molecular orbitals of VO(acac)2 complex. This causes the pyridine to be trans to the V=O bond. Also, this bonding of the electrons donated will increase the electron density of the vanadiums d orbitals which will decrease the p Ï€ → d Ï€ donation from oxygen atom to the vanadium atom in the V=O bond. This result in the falls of the bond order of the complex and the lowering of the bond strength which also lengthen the V=O bond length. Overall, there is decrease of energy need to stretch the V=O bond and thus lead to the shifting of the V=O stretching vibration to lower frequency in the spectrum. This also further proven that the VO(acac)2py has an octahedral structure. Also, there is the delocalization of the Ï€ electrons from the aromatic ring of the pyridine which able to stabilize the complex more and decrease the p Ï€ → d Ï€ donation from oxygen to vanadium in the V=O bond. This make the vanadium-pyridine complexation more feasible and stable that result in the stronger V-N stretching bond which gain partial double bond character. As a result of the inter-electron repulsion, the electron density of the V=O bond is then shifted towards the oxygen atom and cause the weakening of the V=O double bond that cause the bond to loses the characteristic of the double bond nature. Thus, lesser energy is needed to stretch the weakened and lengthened V=O bond and lead to the shifting of the frequency of the spectrum. There is also the reason of the trans influence where the trans influence is the effect of pyridine ligand that weakens the bond that is trans to itself in the complex. The electrons of the oxo-ligand in the axial position of the complex occupies the dz2 orbital that will cause new binding ligand to form coordinate bond with the vanadium ion to be trans position to the oxo ligand. Pyridine ligand have donate electrons to the VO(acac)2 complex metal center and reside in the 3dz2 orbital from the site trans to the oxygen atom which causes repulsion. Therefore, the pyridine ligand and the oxo-ligand are in the trans position to each other which uses the same orbitals on the metal vanadium ion for bonding. However, the oxygen atom cannot donate the electrons to the metal as well as the pyridine ligand which causes the V=O bond to be weaker. Therefore, both axial bonds to the vanadium are weakened and lengthened which decrease the force constant (k) and decrease the stretching frequency. The shift also helps to confirm the presence of VO(acac)2py. On the other hand, the VO(acac)2py spectrum found in Appendix 2 have showed peak of 998.04 cm-1 which has a small different to the 997.7cm-1 peak found in the VO(acac)2 spectrum. This shows that there is still presence of VO(acac)2 in the product. Also the literature value of the V=O stretching bond of the VO(acac)2 is found out to be 995 cm-1 which is close to the 997.7 cm-1 in the product spectrum. These further prove that the VO(acac)2 is present. This can explain for the relatively low yield of 58.5% of the VO(acac)2py synthesis as the reaction has not gone into completion. However, comparing the intensity of the peak of 997.7 cm-1 and 966.04 cm-1 which indicate V=O bond in VO(acac)2 and VO(acac)2py complex respectively, there is higher intensity of the 966.04cm-1 which show that more pyridine adduct is formed in product. This also shows that the reaction may be an equilibrium reaction where both product and reactant can be present. This result can also be interpreted as the reac tion is not complete and more reflux time or higher temperature for reflux is needed to carry out to ensure more products formed. Lastly, there is a broad low intensity peak at 3449.72 at the VO(acac)2py spectrum found in Appendix 2 which was due to the presence of water that may be caused by insufficient drying of the VO(acac)2py product. Observation of Color changes During the synthesis of the complex, there is a series of observation of color changing of the compound in the solution. The color changes observed during the synthesis of the VO(acac)2 is due to the change of the oxidation state of V2O5 (oxidation state of V = +5). The orange powder of V2O2 is being reacted with the H2O and H2SO4 to reduce to a dark green solution of [V(H2O)5]3+ (oxidation state of V= +3) complex during middle of the vigorous reflux. When the reflux is complete, the solution was in dark blue color which is due to the reduction of the remaining V2O5 to dark blue [VO(SO4)(H2O)5] complex (oxidation state of V = +4). During the forming of the pyridine adduct, the dark blue VO(acac)2 is changed to dark green VO(acac)2py complex. This color changing phenomenon can also be explained using the Crystal Field Theory mentioned. Electrons of the two different energy level orbitals can be excited with à ¢Ã‹â€ Ã¢â‚¬  o energy. The higher the oxidation state, there will be more different between the two splitting energy levels which therefore lead to higher à ¢Ã‹â€ Ã¢â‚¬  0. For V2O5 (oxidation state of V = +5) will have a higher à ¢Ã‹â€ Ã¢â‚¬  0 and hence will absorbs light of the electromagnetic spectrum of higher energy with higher frequency and reflect low energy light. Therefore, V2O5 will absorb the blue-green light of higher energy and reflect orange of lower energy light which is shown off as orange with naked eyes. When there is a reduction of the compound to VO(acac)2 or VO(acac)2py compound, the light absorbed was at lower frequency and light reflected was of higher frequency such as blue-green and thus, there is the change of orange powder to blue-green product. Therefore, VO(acac)2 and VO(acac)2py appe ared as blue-green compounds. Possible Limitations and Sources of Errors in Experiment There are several limitations of the experiment that result in not having 100% yield of the product of both VO(acac)2 and VO(acac)2py complexes. Firstly, there may be loss of product due to the cotton wool filtration that causes some of the filtrate to be trapped in the cotton wool and unable to pass through. Secondly, according to the Le-Chateliers principle, for the Reaction 2, if there is an increase in the H+ concentration, reaction will shift the concentration of the reaction to the left which result in lesser product produce. When the reaction mixture is added slowly to the alkaline sodium carbonate solution, incomplete neutralization may occur where not all H+ are removed, and hence lesser product is produced. Therefore, longer cooling time will be needed for re-crystallization so as to allow more crystallization of VO(acac)2 and push the reaction to the right. Another limitation is of using of the sulphuric acid, H2SO4 may result in the reduction of the VO2+ ions to V3+ ions which decrease VO2+ ions available for product of VO(acac)2 formations. The lower percentage yield of the VO(acac)2py may be due to incomplete refluxing and thus lead to low yield obtained. Also, impurities may be present in the VO(acac)2 product produced that observed at the bottom of the flaks which lead to false weight measured and inaccurate percentage calculated. The round bottom flask should be swirled every fifteen minutes during the reflux which can prevent the settling of the V2O5 solid at the bottom of the flask and identifying impurities. The yield of the VO(acac)2py can be improved with addition of excess pyridine and increase the reflux time. Possible Precaution in Experiment For the synthesis of the VO(acac)2 complexes, there is a step of the adding of ethanol into the mixture of solution for reflux. Ethanol was used as solvent. The metal vanadium atom is surrounded by non-polar ligands of acetylacetonate or pyridine in second part of the experiment. Ethanol is more non-polar than water and will form solvent-solute interactions with the complexes and dissolve those ligands for better interaction in the solution. The use of the ethanol also helps to separate the VO(acac)2 from the insoluble V2O5 residue that will be filtered and remain in the cotton wool during filtration. Also, ethanol was used to prevent side reaction that will arise so as to increase the yield of the product. From reaction 1, there is the reaction of the V2O5 and the H2SO4 to produce the intermediate VO2+ ion that besides reacting with the acetylacetonate in reaction 2, VO2+ can react with the water and oxygen molecules by-product formed from reaction 1. It is as shown in Reaction 3. The side reaction will decrease the amount of VO2+ available for reaction with the acetylacetonate in reaction 3 to form product of VO(acac)2. This will decrease the amount of yield of the product produced. 4VO2+ + 2H2O + O2  ® 4VO2+ + 4H+ Reaction 3 However, this side reaction can be reduced with the addition of ethanol where ethanol will react with oxygen and produce acetaldehyde as shown: C2H5OH +  ½O2  ® CH3CHO + H2O Reaction 4 Also, using vacuum to remove the oxygen and water formed can be a good way to reduce problem of side reaction with VO2+. Another precaution taken was adding drop wise of the acetylacetonate to ensure sufficient reaction time and prevent influx of the H+ concentration and shift the equilibrium to the left and decrease the yield of the product formed. Anhydrous sodium carbonate, Na2CO3, was dissolved in water so as to form alkaline solution to neutralise H+ ions so as to shift the acetylacetonate toward the enol form. This will increase the formation of the VO(acac)2 products. Also, the mixture solution was added slowly to the sodium carbonate solution so as to prevent the rapid foaming caused by the product of CO2 and lose of product due to overflowing. Also, slowly adjusting the pH with more alkaline environment and less mixture solution allows the reaction to react at steady pace and reduce any side reaction to occur. Conclusion The percentage yield of the product of VO(acac)2 and VO(acac)2py complex were 77.8% and 58.5% respectively. From the IR spectrum of VO(acac)2py, it is shown that the V=O bond have shifted from 9998.04 cm-1 to 966.04 cm-1. This shifting of the peak indicate the formation of the pyridine adduct, VO(acac)2py, with the decrease in the wavenumber of the V=O stretching band.